Novel HEXOL-type cyclometallated iridium(III) complexes: stereoselective synthesis and structure elucidation.

نویسندگان

  • Liangru Yang
  • Alex von Zelewsky
  • Helen Stoeckli-Evans
چکیده

Two diastereoisomers of tetranuclear cyclometallated iridium complexes, either having an inner core of HEXOL-type [Ir(IrCl2)3]6+ unit and a surface of six chiral, didentate, cyclometallated ligands, are stereoselectively synthesized from an enantiopure pinenopyridine derivative.

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عنوان ژورنال:
  • Chemical communications

دوره 33  شماره 

صفحات  -

تاریخ انتشار 2005